from an integrity point of view I suspect they would outlive us all.
The standard plumbing grade is expected to be 50+ years and the grade we use has a larger wall thickness, so it won't be my problem
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As to whether the internal surface will degrade sooner than that and cause issues, I'd say unlikely but who knows.
Chemical analysis won't show anything but maybe micro if it gave the bugs a chance to get a foothold? probably still wouldn't see anything if you're running loop heat every night.
Our oldest is a similar age to Gareth's, but I think the original loop is still in place from the mid-nineties in Dundee. One of the first central loops I'm aware of.
Fraser